You can save PDF documents for yourself in Order Printer Pro, in a couple of ways:
Export a PDF for a single order
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In your Shopify admin
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Go to the Orders section
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Click on an order to open it
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In the "More actions" dropdown, select Export PDF with Order Printer Pro
Export PDFs for multiple orders
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In your Shopify Admin
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Go to the Orders section
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Put a checkmark on the orders you want to export as PDFs
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In the actions bar, click on the three dots, select Export PDFs with Order Printer Pro

Note: You can select and export a maximum of 50 orders at a time. The 50 order limit is something that Shopify controls, and apps unfortunately cannot change that limit.